Esuka Hibino is the major antagonist of Cardfight!! Vanguard: Shinemon. She is the owner of the Esuka Corporation, who bought Card Capital and plans to remodel the shop into one of her card shop chain locations. She was also once a well-known swimsuit model.
She is determined to stop Shinemon Nitta's rebellion, as she bought Card Capital for her own organization after the death of Misaki Tokura's parents. She seems to harbor no ill will, however, as her chain of card shops are known for being beginner-friendly, with a cozy environment for all kinds of cardfighters, and even cares for Shinemon, noting that his studies may suffer because of his actions.
She extremely hates cats, and might even be afraid of them.
She wears a dark mauve suit jacket with gold inlay and a long, flowy pink dress. She wears a frilly white shirt underneath her jacket. Her hair is pink and very long, and her eyes are green. Her heels are the same shade of mauve, and are tipped and soled with gold.
- She may be related to Arte Hibino in some way. This is supported by not only their shared surname, but also due to the inclusion of Ruga Kaizu in the Shinemon Arc who, like Arte, was a Diffride vessel, as well as the inclusion of other Cardfight!! Vanguard G characters into the V Series.
- In the Japanese version of the anime, she is known as a Gravure model, which is a more adult-oriented model that is intended to be provocative, and not outright sexual. The English dub and subtitles changed this due to cultural differences on mature themes.